Some Regularities Inherent in the Balance 2∙f(O) – f(H) Formulated for an Electrolytic System with Symproportionation Reactions Involved

نویسندگان

چکیده

The general properties of the balance f12 = 2∙f(O) – f(H), as linear combination elemental balances: f1 f(H) for H and f2 f(O) O, formulated electrolytic systems, are presented. These properties/regularities inherently related to (LC) with charge (f0) other elemental/core balances fk f(Yk) (Yk ≠ H, O), expressed by, where multipliers dk involved oxidation numbers (ONs) elements in system question. dependence or independence from f0,f3,…, fK, by LC, provides criterion distinguishing between non-redox redox systems. is primary form Generalized electron (GEB), completing set K independent f0,f12,f3,…,fK needed solution a according GATES/GEB principles. For system, K–1 equations f0,f3,…,fK required. In this formulation, terms: ONs, oxidant, reductant, equivalent mass derivative/redundant concepts. illustrated here symproportionation reactions occur.

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ژورنال

عنوان ژورنال: Academic journal of chemistry

سال: 2021

ISSN: ['2519-7045', '2521-0211']

DOI: https://doi.org/10.32861/ajc.61.1.11